Ren Xin, Chen Weiguo, Zhu Xihai. A Study on Separation Mechanism of Solvent Sublation[J]. Acta Scientiarum Naturalium Universitatis SunYatseni, 1996,35(6):24-29.
Ren Xin, Chen Weiguo, Zhu Xihai. A Study on Separation Mechanism of Solvent Sublation[J]. Acta Scientiarum Naturalium Universitatis SunYatseni, 1996,35(6):24-29.DOI:
Ni BDODO) as the objects of the solvent sublation (SS) were studied. The IR data showed that the separation efficiency of the SS was independent of the interreaction between sublate and organic solvent. The bubble absorption of the SS was the key to the separation efficiency. The SS processes of the sublates was obedience to first order kinetics. A new characteristic parameter
apparent activation energy of attachment of the sublate to bubble
had been proposed to describe the separation efficiency of the solvent sublation. The value of E f depended on the surface activity of the sublate so that the HLB value of the sublate was used for the indication of E f. Lower HLB value corresponded to higher surface activity and lower E f
as well as larger bubble adsorption capacity and higher separation efficiency.