Electroreduction of Samarium ion on the Fe Cathode in Molten Chlorides

Tong Yexiang; Yang Qiqin; Liu Guankun; Zhong Qizhi

您当前的位置：

首页 >

文章列表页 >

Electroreduction of Samarium ion on the Fe Cathode in Molten Chlorides

更新时间：2023-12-11

- Electroreduction of Samarium ion on the Fe Cathode in Molten Chlorides
- Acta Scientiarum Naturalium Universitatis SunYatseni Vol. 35, Issue 2, Pages: 67-70(1996)
- 作者机构：
  
  中山大学化学系
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Published：1996，
  
  Published Online：25 February 1996，
扫描看全文
Tong Yexiang, Yang Qiqin, Liu Guankun, et al. Electroreduction of Samarium ion on the Fe Cathode in Molten Chlorides. [J]. Acta Scientiarum Naturalium Universitatis SunYatseni 35(2):67-70(1996)
DOI：

Tong Yexiang, Yang Qiqin, Liu Guankun, et al. Electroreduction of Samarium ion on the Fe Cathode in Molten Chlorides. [J]. Acta Scientiarum Naturalium Universitatis SunYatseni 35(2):67-70(1996) DOI：

摘要

利用线性扫描伏安法研究了Ｓｍ（Ⅲ）在等摩尔ＭａＣｌ－ＫＣｌ熔体中铁电极上还原的电化学行为．结果表明，Ｓｍ（Ⅲ）第一步可逆还原为Ｓｍ（Ⅱ），Ｓｉｎ（Ⅱ）进一步还原并与铁形成合金．测定了Ｓｍ（Ⅲ）在氧化物熔体中的扩散系数及扩散活化能．

Abstract

Linear sweep voltemmetry has been used to study the electrochemical reac tion of Sin(Ⅲ) in molten equimolar NaCl-KCl on the Fe cathode. The results suggest that Sin(Ⅲ) ions is reduced to Sm(Ⅱ) on Fe electrode at the first step

subsequently reduced to Sin(O) and formed alloy with Fe on Fe electrode surface. The diffusion coefficients and diffusion activation energy of Sin(Ⅲ) in molten chlorides had been determined.

关键词

钐离子电还原熔盐

Keywords

samarium ionelectroreductionmolten salt

references

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Molecular dynamics simulations of thermophysical properties enhancement of chloride molten salt based nanofluid

Molecular dynamics simulations of thermophysical properties of binary carbonate molten salt at nickel oxide surface

Related Author

LI Rong

LIANG Fei

DING Jing

LIU Shule

PAN Junxi

DING Jing

LIU Shule

Rong LI

Related Institution

School of Materials Science and Engineering，Sun Yat-sen University

School of Materials Sciences and Engineering， Sun Yat-sen University

Postal code：510275
Tel：020-84112585，84113223 Email：xuebaozr@mail.sysu.edu.cn
Technical support is provided by Beijing Founder electronics co., LTD 京ICP备09064830号-19 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰