Reaction of Transition Metal Thiolato Units──"Synthons"Ⅰ. Crystal Structure of Cluster Complex Co3 （abt）3（μ3-S） （PBu3￣n）3

Kang Beisheng; Chen Zhongning; Zhou Zhongyuan; Tong Yexiang; Yu Xiaolan

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Reaction of Transition Metal Thiolato Units──"Synthons"Ⅰ. Crystal Structure of Cluster Complex Co3 （abt）3（μ3-S）（PBu3￣n）3

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- Reaction of Transition Metal Thiolato Units──"Synthons"Ⅰ. Crystal Structure of Cluster Complex Co3 （abt）3（μ3-S）（PBu3￣n）3
- Acta Scientiarum Naturalium Universitatis SunYatseni Vol. 35, Issue 3, Pages: 127-128(1996)
- 作者机构：
  
  1. 中山大学化学系
  2. 中国科学院成都有机化学研究所
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Published：1996，
  
  Published Online：25 May 1996，
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Kang Beisheng, Chen Zhongning, Zhou Zhongyuan, et al. Reaction of Transition Metal Thiolato Units──"Synthons"Ⅰ. Crystal Structure of Cluster Complex Co3 （abt）3（μ3-S）（PBu3￣n）3. [J]. Acta Scientiarum Naturalium Universitatis SunYatseni 35(3):127-128(1996)
DOI：

Kang Beisheng, Chen Zhongning, Zhou Zhongyuan, et al. Reaction of Transition Metal Thiolato Units──"Synthons"Ⅰ. Crystal Structure of Cluster Complex Co3 （abt）3（μ3-S）（PBu3￣n）3. [J]. Acta Scientiarum Naturalium Universitatis SunYatseni 35(3):127-128(1996) DOI：

摘要

含硫过渡金属基元ＣｏＬＬ的反应──Ⅰ．簇合物Ｃｏ

３

Abstract

The construction of three of the structural unit Co(abt) ( ) (abbreviated as MLL

obtained from CoCl2

abtNa and

abt = o - aminobenzenethiolate) in the presence of Li2S forms the tricobalt-phosphine-thiolato cluster complex Co3 (abt )3 (μ3-S ) ( )3. The triangular Co3molecular plane is capped by an inorganic μ3-S and each penta-coordinated Co atom is further ligated by a phosphine and an abt ligand to form a distorted trigonal bipyramid. Each of the thiolato sulfur atoms bridges the adjacent Co atoms to give a μ2-S bridge resulting in an average Co-Co distance of 0. 270 9 nm.

关键词

&nbsp三核钴簇合物基元反应晶体结构膦硫混合配位

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