Synthesis and Characterization of Oxovanadium(Ⅳ) Carboxylate Coordination Compounds

Zheng Chenmou; Luo Yuji; Huang Kunyao

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Synthesis and Characterization of Oxovanadium(Ⅳ) Carboxylate Coordination Compounds

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- Synthesis and Characterization of Oxovanadium(Ⅳ) Carboxylate Coordination Compounds
- Acta Scientiarum Naturalium Universitatis SunYatseni Vol. 35, Issue S2, Pages: 5-9(1996)
- 作者机构：
  
  中山大学化学系
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Published：1996，
  
  Published Online：25 December 1996，
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Zheng Chenmou, Luo Yuji, Huang Kunyao. Synthesis and Characterization of Oxovanadium(Ⅳ) Carboxylate Coordination Compounds. [J]. Acta Scientiarum Naturalium Universitatis SunYatseni 35(S2):5-9(1996)
DOI：

Zheng Chenmou, Luo Yuji, Huang Kunyao. Synthesis and Characterization of Oxovanadium(Ⅳ) Carboxylate Coordination Compounds. [J]. Acta Scientiarum Naturalium Universitatis SunYatseni 35(S2):5-9(1996) DOI：

摘要

合成了三水乳酸氧钒（Ⅳ）、二水苹果酸氧钒（Ⅳ）、己二酸氧钒（Ⅳ）和二苹果酸氧钒（Ⅳ）铵４种羧酸氧钒（Ⅳ）配合物，应用元素分析、热分析和红外光谱分析对它们的结构进行表征．较详细地讨论了它们的红外光谱

Abstract

VO[(CH 3CH(OH)CO 2) 2(H 2O) 2]·H 2O

VO[CO 2CH(OH)CH 2CO 2(H 2O) 2]

VO(CO 2(CH 2) 4CO 2)and (NH 4) 2[VO(CO 2CH(OH)CH 2CO 2) 2] were synthesized and characterized by elemental analyses

DTA

TG and IR. Their infrared frequencies were discussed and assinged applying group theory. Thermal decomposition processes of the compounds were also discussed according to assigned infrared frequencies of certain bonds of the compounds.

关键词

羧酸氧钒（Ⅳ）配合物热分析IR光谱

Keywords

oxovanadium(Ⅳ) carboxylate coordination compoundsthermal decompositioninfrared frequencies

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